VIRO GROUP-MISSIMER & ASSOCIATES
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PHASE II ENVIRONMENTAL SITE ASSESSMENT
DREW PARK SITE
CLEARWATER, FLORIDA
Prepared for:
King Engineering Associates, Inc,
5440 Beaumont Center Boulevard
Suite 460
Tampa, Florida 33634
Prepared by:
ViroGroup, Inc.jMissimer Division
5909-0 Hampton Oaks Parkway
Tampa, Florida 33610
February, 1993
Project Number
03-01904.00
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M&A
MISSIMER 8\ ASSOCIATES, INC.
Environmental and Groundwater Services
5909,D Hampton Oaks Parkway
Tampa, Florida 33610
(813) 623-5123
Fax (813) 620-4586
February 25, 1993
Ms. Melisa Reiter
Environmental Scientist
King Engineering Associates, Inc.
5440 Beaumont Center Boulevard
Suite 460
Tampa, Florida 33634
Dear Ms. Reiter:
Introduction
ViroGroup, Inc., Missimer Division (Missimer) was contracted by King
Engineering Associates, Inc. (KEA) to perform groundwater sampling as part of a
Phase II Environmental Site Assessment on the Drew Park Site in Clearwater,
Florida.
The scope of services for this project included the installation of three monitor
wells (placement determined by KEA), organic vapor analysis (using the
headspace technique) of soils obtained from each monitor well (MW) location,
the assessment of groundwater flow direction on the subject site and the analysis
of a groundwater sample obtained from each MW for the following parameters:
. Purgeable Aromatics (EPA Method 624)
. Organochlorine Pesticides and PCBs (EPA Method 608)
. Base Neutrals/Acid Extractables (EPA Method 625)
. Cyanide
. Nitrate/Nitrite Nitrogen
. Phenols
. Antimony (total)
. Arsenic (total)
. Beryllium (total)
. Cadmium (total)
HOUSTON . MIAMI . TAMPA . JACKSONVILLE . PALM BEACH GARDENS . CAPE CORAL
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Ms. Melisa Reiter
February 25, 1993
Page 2
. Chromium (total and dissolved)
. Copper (total)
. Lead (total and dissolved)
. Mercury (total and dissolved)
. Nickel (total and dissolved)
. Selenium (total)
. Silver (total)
. Thallium (total)
. Zinc (total)
Field Activities
On January 7, 1993, M&A supervised the installation and development of the
three MWs on the subject site. Soil samples collected from approximately one
foot below land surface and extending to the water table at each boring location
were analyzed for volatile organic vapors using an organic vapor analyzer (OVA)
with a flame ionization detector. The MWs were fitted with locking caps and
allowed to stabilize overnight.
On January 8, 1993, M&A collected a groundwater sample from each MW for
laboratory analyses. A total of five well volumes was purged from each MW prior
to sample collection. A dedicated bailer supplied by the laboratory was used to
collect the groundwater sample from each MW. Representatives from KEA were
on the site on January 8, 1993 to survey the top of casing elevation of each MW.
The groundwater level was measured for each MW prior to purging.
An additional site visit was made on January 29, 1993 to obtain a total and
dissolved groundwater sample from each MW for chromium, lead, mercury and
nickel. A total of five volumes of water was purged from each MW prior to
sample collection. A dedicated bailer supplied by the laboratory was used for
each MW.
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Ms. Melisa Reiter
February 25, 1993
Page 3
Results
A net OVA result of 0.5 parts per million was recorded for the sample collected at
one foot for soil boring 1 (MW-1). No OVA reading was recorded for the
remaining soil samples analyzed. The net OVA reading subtracts out that portion
of the OVA reading that is attributed to naturally occurring methane vapors.
Copies of the complete analytical reports are included as attachments to this
report. The initial round of analyses indicated chromium, lead and mercury levels
exceeded Florida primary drinking water standards in each MW. In addition, the
nickel concentration in MW-2 exceeded the primary drinking water standard.
Nitrate-nitrite nitrogen concentrations were detected in each MW. The nitrate-
nitrite nitrogen concentration in MW-1 and MW-2 exceeded the primary drinking
water standard. The nitrate-nitrite nitrogen concentration in MW-3 did not exceed
the primary drinking water standard. Cyanide was detected in MW-3 at a
concentration below the primary drinking water standard.
The results of the second round of groundwater analyses indicated that the total
chromium and lead concentrations exceeded the primary drinking water
standards in all MWs. The mercury concentration exceeded the primary drinking
water standards in MW-1. The total nickel concentrations were below the
primary drinking water standards for all MWs. The dissolved metal
concentrations were below the method detection limits for the tested metals in all
MWs.
The relative top of casing elevation and the depth to groundwater was
determined for each MW. This information was used to assess the water table
elevation and the direction of groundwater flow in the surficial aquifer system at
the subject site. The data indicate the direction of groundwater flow at the
subject site is to the northeast at a gradient of 0.01 foot per foot.
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Ms. Melisa Reiter
February 25, 1993
Page 4
Conclusions and Recommendations
The concentrations of chromium, lead, mercury and nickel detected in the first
round of analyses appear to have been adsorbed to suspended solids present in
the groundwater and were not dissolved in the groundwater. This is verified
since the concentrations of these metals were below method detection limits
when the groundwater was field filtered prior to analyses.
To assess if the elevated metal and nitritate-nitrite nitrogen concentrations are
indicative of regional influence and not site specific influences, it is suggested to
collect and analyze a background groundwater sample for total and dissolved
chromium, lead, mercury, nickel, nitrate nitrogen and nitrite nitrogen from a
temporary monitor well. The nitrogens should be analyzed individually since
each nitrogen has its own established primary drinking water standard.
Missimer appreciates this opportunity to be of service to KEA. If you have any
questions or comments, please call our office.
Sincerely,
~
Kurt M. Juntunen, GEl
Scientist
.~ Dale ~. Jenkins,
-. Lie. '.:"".en6,.e_d.'.,~. Rrofessional !
' ,Geotc~~;,,# 1286 ;z!:zu 1?
KMJ:DRJ:SOla
03,01904,00
Attachments
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TABLE 1
DREW PARK SITE
CLEARWATER, FLORIDA
GROUNDWATER ANALYTICAL SUMMARY
Round Analtye MW-1 MW-2 MW-3 Florida Primary
(ug/L) 1 Drinking Water
Standards2 (ug/L)
First Total Chromium 540 450 270 100
Total Lead 24 250 95 15
Total Mercury 3 6 3 2
Total Nickel 72 110 50 100
Second Total Chromium 240 310 360 100
Total Lead 140 40 120 15
Total Mercury 3 ND3 NO 2
Total Nickel 65 51 68 100
Dissolved Chromium NO NO NO 100
Dissolved Lead NO NO NO 15
Dissolved Mercury NO NO NO 2
Dissolved Nickel NO NO NO 100
1 ugjL: micrograms per liter
2 Chapter 17-550.310, Florida Administrative Code, January 1993
3 NO: Not Detected
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AUDIT
SITE
MiA
""
"" PINELLAS
"" COUNTY
""
""
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CULF
OF
UC.A7CO
/
/
/
/
/
/
/
/
/
TAHPA
BAY
SCALE
~~
o 3 MIlLS
ElVVIBOlVNEH7'AL ANlJ GBO{/lVlJ lYA J'EB SEBVICES
DRN. BY: MJL DWG NO. 31904SLM DATE: 02 24 93
PROJECT NAME: DREW PARK SITE NUMBER: 03-01904.00
Misscner I
Associates,Inc.
FIGURE 1. SITE VICINITY MAP
-------------------
MW-1
SB-1
@
24.29
,
'<'it
.<9
.M&A
--------
LEGEND
MONITOR WELL AND SOIL BORING
LOCATION, NUMBER AND WA TER-
TABLE ELEVATION IN FEET
GROUNDWATER FLOW DIRECTION
WATER TABLE CONTOUR AND
ELEVATION IN FEET
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CONTOUR INTERVAL: 2.35 FEET
/
MW-2
SB-2
@
27.42
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.__._--1
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"=P:E~TY-
LINE
W-1
Sft-1
:)~9
,--
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~J . ~
'6'
-'~
DREW STREET
EHW..ROHNEHrAl AH'LJ G..ROOHlJ!fA TER SERVICES
------ -- -----.---------"-----------. ----
DRN. BY: MJL DWG NO, 31904SIT DATE: 02/24/93
PROJECT NAME: DREW PARK SITE PROJECT NUMBER: 03-01904.00
FIGURE 2. SITE MAP
SCALE
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o 300
FEET
Missimer
&
Associates,Inc.
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WADSWORTH/ALERT Laboratories
Division of Enseco Incorporated
5910 Breckenridge Parkway, Suite H 813-621-0784
Tampa, FL 33610 FAX 813,623-6021
ANALYTICAL REPORT
PROJECT NUMBER 03-01904
DREW STREET SITE
29 JANUARY 1993
Presented to:
JERRY REEVES
MISSIMER & ASSOCIATES, INC.
ENSECO-WADSWORTH/ALERT LABORATORIES
O,,(Lvv~\.i. UNIJ;t{JdY,-
(J;oanne Anderson
Project Manager
Laboratory Direc
February 12, 1993
A Corning Company
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.
ENSECO-VVADSVVORTH/ALERT
Labontorils
INVOLVEMENT
This report summarizes the analytical results of the Drew street
site submitted by Missimer & Associates, Inc. to Enseco-
Wadsworth/ALERT Laboratories who provided independent, analytical
services for this project under the direction of Jerry Reeves. The
samples were accepted into Wadsworth's Florida facility on 29
January 1993, in accordance with documented sample acceptance
procedures. The associated analytical methods and sample results
are outlined sequentially in this report.
Analytical results included in this report have been reviewed for
compliance with the Laboratory QA/QC Plan as summarized in the
Quality Control section at the rear of the report. Sample custody
documentation describing the number of samples and sample matrices
is also included. Any qualifications and/or non-compliant items
have been noted below.
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ENSECO-WADSWORTH/ALERT
Laboratories
ANALYTICAL METHODS
Wadsworth/ALERT Laboratories utilizes only USEPA approved analytical methods and
linstrumentation. The analytical methods utilized for the analysis of these
samples are listed below.
I PARAMETER METHOD
, ---------------------------------------------------------------------------------
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I Chromi um
Lead
IMerCUry
Nickel
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I NOTE:
I (D)
EPA Methods
I Std. Methods
I USEPA Methods
SW846 Methods
I ASTM Methods
NIOSH Method
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METALS
** EPA Method 200.7
** EPA Method 239.2
** EPA Method 245.1
** EPA Method 200.7
** Indicates usage of this method to obtain results for this
report.
Indicates draft version of this method was used
Methods for Chemical Analysis of Water and Wastes, USEPA, 600/4-
79-020, March, 1983. July, 1982
Drinking Waters USEPA, 600/4-88/039, December, 1988.
Standard Methods for the Examination of Water and Waste-water,
APHA, 16th edition, 1985.
From 40CFR Part 136, published in Federal Register on October
26, 1984.
Test Methods for Evaluating Solid Waste Physical/Chemical
Methods, 3rd Edition, USEPA, 1986.
American Society for Testing and Materials.
NIOSH Manual of Analytical Methods, National Insti tute for
Occupational Safety and Health, 2nd Edition, April 1977.
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I ENSECO-WADSWDRTH/ALERT
Labontories
ICOMPANY : MISSIMER
LAB #: 3A2914-1
MATRIX : WATER
ISAMPLE ID : MW-1
& ASSOCIATES, INC. DATE RECEIVED: 1/29/93
03-01904
I
CERTIFICATION #: E84059
METALS ANALYTICAL REPORT HRS84297
SELECTED LIST
ITotal metals analysis results - as received
I ELEMENT
PREPARATION - DETECTION
ANALYSIS DATE RESULT LIMIT
2/ 9- 2/10/93 240 50 ug/L
2/ 9- 2/10/93 3 2 ug/L
2/ 9- 2/10/93 65 50 ug/L
2/ 9- 2/10/93 140 20 ug/L
IChromium
Mercury
Nickel
ILead
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INOTE:
NO
(None Detected)
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ii ENSECO-WADSWORTH/ALERT
laboratories
ICOMPANY : MISSIMER & ASSOCIATES,
LAB #: 3A2914-2
MATRIX : WATER
I SAMPLE ID : MW-1 FILTERED
INC.
DATE RECEIVED:
1/29/93
03-01904
I
CERTIFICATION #: E84059
METALS ANALYTICAL REPORT HRS84297
SELECTED LIST
ITota1 metals analysis results - as received
I ELEMENT
I Chromi um
Mercury
Nickel
I Lead
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ND
(None Detected)
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PREPARATION - DETECTION
ANALYSIS DATE RESULT LIMIT
2/ 9- 2/10/93 ND 50 ug/L
2/ 9- 2/10/93 ND 2 ug/L
2/ 9- 2/10/93 ND 50 ug/L
2/ 9- 2/10/93 ND 5 ug/L
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. ENSECO-WADSWDRTH/ALERT
Laboratories
ICOMPANY : MISSIMER & ASSOCIATES, INC.
LAB #: 3A2914-3
MATRIX : WATER
ISAMPLE ID : MW-2
DATE RECEIVED: 1/29/93
03-01904
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METALS ANALYTICAL REPORT
SELECTED LIST
CERTIFICATION #: E84059
HRS84297
ITota1 metals analysis results - as received
I ELEMENT
IChromium
Mercury
Nickel
ILead
PREPARATION - DETECTION
ANALYSIS DATE RESULT LIMIT
2/ 9- 2/10/93 310 50 ug/L
2/ 9- 2/10/93 ND 2 ug/L
2/ 9- 2/10/93 51 50 ug/L
2/ 9- 2/10/93 40 10 ug/L
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INOTE:
ND
(None Detected)
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I ENSECO-WADSWDRTH/ALERT
Laboratories
ICOMPANY : MISSIMER & ASSOCIATES,
LAB #: 3A2914-4
MATRIX : WATER
ISAMPLE ID : MW-2 FILTERED
INC.
DATE RECEIVED:. 1/29/93
03-01904
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CERTIFICATION #: E84059
METALS ANALYTICAL REPORT BRS84297
SELECTED LIST
ITotal metals analysis results - as received
I
ELEMENT
PREPARATION - DETECTION
ANALYSIS DATE RESULT LIMIT
2/ 9- 2/10/93 ND 50 ug/L
2/ 9- 2/10/93 ND 2 ug/L
2/ 9- 2/10/93 ND 50 ug/L
2/ 9- 2/10/93 ND 5 ug/L
I Chromium
Mercury
Nickel
I Lead
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I NOTE:
ND
(None Detected)
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~ EIISECO-WADSWlIII1IIIAI!RT
. Laboratories
I COMPANY : MISSIMER & ASSOCIATES, INC.
LAB #: 3A2914-S
MATRIX : WATER
I SAMPLE ID : MW - 3
DATE RECEIVED: 1/29/93
03-01904
I
METALS ANALYTICAL REPORT
SELECTED LIST
CERTIFICATION #: E84059
HRS84297
ITota1 metals analysis results - as received
I ELEMENT
I Chromi um
Mercury
Nickel
I Lead
PREPARATION - DETECTION
ANALYSIS DATE RESULT LIMIT
2/ 9- 2/10/93 360 50 ug/L
2/ 9- 2/10/93 ND 2 ug/L
2/ 9- 2/10/93 68 50 ug/L
2/ 9- 2/10/93 120 20 ug/L
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I NOTE:
ND
(None Detected)
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liIiIifl ENSECO-WADSWORTH/ALERT
. Laboratories
ICOMPANY : MISSIMER &: ASSOCIATES,
LAB #: 3A2914-6
MATRIX : WATER
ISAMPLE ID : MW- 3 FILTERED
INC.
DATE RECEIVED: 1/29/93
03-01904
I
METALS ANALYTICAL REPORT
SELECTED LIST
CERTIFICATION #: E84059
HRS84297
ITotal metals analysis results - as received
I ELEMENT
IChromi um
Mercury
Nickel
ILead
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rOTE:
NO
(None Detected)
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PREPARATION - DETECTION
ANALYSIS DATE RESULT LIMIT
2/ 9- 2/10/93 NO 50 ug/L
2/ 9- 2/10/93 NO 2 ug/L
2/ 9- 2/10/93 NO 50 ug/L
2/ 9- 2/10/93 NO 5 ug/L
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Ii ENSECO-WADSWDRTH/ALERT
Laboratories
I COMPANY : MISSIMER << ASSOCIATES,
LAB #: 3A2914-7
MATRIX : WATER
I SAMPLE ID : EQUIPMENT BLANK
INC.
DATE RECEIVED:, 1/29/93
03-01904
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CERTIFICATION #: E84059
METALS ANALYTICAL REPORT HRS84297
SELECTED LIST
I Total metals analysis results - as received
I
ELEMENT
PREPARATION - DETECTION
ANALYSIS DATE RESULT LIMIT
2/ 9- 2/10/93 ND 50 ug/L
2/ 9- 2/10/93 ND 2 ug/L
2/ 9- 2/10/93 ND 50 ug/L
2/ 9- 2/10/93 ND 5 ug/L
I Chromium
Mercury
Nickel
I Lead
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INOTE: ND
(None Detected)
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ENSECO-WADSWDRTH/ALERT
Laboratories
QUALITY CONTROL SECTION
. Quality Control Summary
. Laboratory Blanks
. Laboratory Control Sample
. Matrix Spike/Matrix Spike Duplicate Results
. Sample Custody Documentation
Irtterdepartment Correspondence Sheet
CITY OF CLEARWATER
TO:
Art Kader, Assistant Director/Parks & Recreation Dept.
Tenry Finch, Environmental Program Supervisor g
Tom Miller, Asst. Director of PW/Environmental
FROM:
.COPIES:
SUBJECT:
Drew Street Park Site, Environmental Assessment
DATE:
February 18, 1993
I have reviewed the latest results of the monitor well groundwater
testing performed at the proposed park site on Drew Street by King
Engineering.
I concur with the King Engineering Memorandum of February 16, 1993,
from Doug Robison to Ed Mazur, which recommends that no additional
testing or remediation of the site is warranted. The metals that
were above guidance concentrations in the unfiltered sample were
not detected in the filtered samples.
The insoluble metals detected in the unfiltered sample may have
come from various sources, such as high clay content soils,
atmospheric deposition, or naturally occurring in some soil types
and not from on-site contamination,
Based on the results of the additional testing, I recommend that
the City move forward on the acquisition of this property.
TF
-
_"H :.......-.... .,..- i
~
~_. ,
Ir(p
~... \c'4---=
'-~". -,._-~" ." ."' .
King Engineering Associates, Inc.
24945 us; Highway 19 North. Clearwater; Florida 34623 . (813) 791-1441 . Fax: (813) 791-9228
Engineers
Planners
Scientists
Surveyors
February 18, 1993
RECEIVED
Mr. Art Kader
Assistant Director
Parks & Recreation Department
City of Clearwater
10 South Missouri Avenue
Clearwater, FL 34616
FEB 18 199J
PIIR/<S AND
RECREATION
Re: Proposed Park Site/Drew Street
Dear Art: ,.
Several weeks ago I brought to your attention the fact that results of the initial groundwater testing
at the Drew Street site indicated that concentrations of several heavy metals warranted a closer
look at the groundwater to determine if those heavy metals bad dissolved into the groU1idwater and,
therefore, become part of the water column. At you direction we obtained three new groundwater
samples. These samples were tested in the filtered and unfiltered state. While the results of the
unfiltered samples were similar to the previous results, the test results of the filtered samples
showed no detection of the heavy metals in question. Copies of the first set of test results were
previously submitted to you, and copies of the latest test results are included with this letter.
Please note that the concentration of these metals were compared to allow rates as indicated in the
U.S. Drinking Water Standards. There are no standards for which to compare concentrations of
any elements in soils. Higher concentrations of metals such as chromium have been found in soils
in many areas of the State of Florida, especially when the soils contain clay. Since it was showrt
that those concentrations were not caused by illegal disposal or dumping of materials, they are
believed to have been caused by atmospheric deposition more commonly known as "add rain".
While we are not able to determine with any certainty how these concentrations occurred on the
Drew Street site, it is our opinion that it is not the result of illegal dumping or disposal of
materials. More than likely, similar concentrations of chromium and lead would be found in
samples taken from sites adjacent to this parcel.
As a result of our investigation, which includes the review of the filtered and non-filtered
groundwater sample analysis (copy attached), it is our opinion that no further testing or
remediation is warranted for this site.
CUrus
Hillsborough
Pasco
Pinellas
~
..
Mr. Art Kader
February 18, 1993
Page Two
,
.
Please let me know if you would like us to discuss this matter with personnel from any other
department within the City of Clearwater. Once you have reviewed our recommendation, if you
concur, please determine whether or not the work that was placed on hold several weeks ago
(boundary survey, concept planning, etc.) should be reauthorized. We will not begin that work until
you tell us to do so.
We appreciate having the opportunity to be of service to the City of Clearwater, and I look forward
to meetlhgwith you, or other members of the City staff, to answer any questions.
fl
Edward Mazur, Jr., P.E.
President
:es
(G:\59\KADER.4)
cc: "'R!mfrWl1~1T'
Doug Robison
Gregg Singleton
File 2110-024-000
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ENSECD-WADSWDRTH/ALERT
Laboratories
QUALITY ASSURANCE / QUALITY CONTROL
PROGRAM SUMMARY
Wadsworth/ALERT Laboratories considers continuous analytical method
performance evaluations to be an integral portion of the data package, and
routinely includes the pertinent QA/QC data associated with various
analytical result reports. Brief discussions of the various QA/QC procedures
utilized to measure acceptable method and matrix performance follow.
Surroqate Spike Recovery Evaluations
Known concentrations of designated surrogate spikes, consisting of a number
of similar, non-method compounds or method compound analogues, are added, as
appropriate, to routine GC and GC/MS sample fractions prior to extraction and
analysis. The percent recovery determinations calculated from the subsequent
analysis is an indication of the overall method efficiency for the individual
sample. This surrogate spike recovery data is displayed alongside acceptable
analytical method performance limits at the bottom of each applicable
analytical result report sheet.
NOTE: Acceptable method performance for Base/Neutral Acid extractables is
indicated by two (2) of three (3) surrogates for each fraction with a minimum
recovery of ten (10) percent each. For Pesticides one (1) of two (2)
surrogates meeting performance criteria is acceptable.
Laboratory Analytical Method Blank Evaluations
Laboratory analytical method blanks are systematically prepared and analyzed
in order to continuously evaluate the system interferences and background
contamination levels associated with each analytical method. These method
blanks include all aspects of actual laboratory method analysis (chemical
reagents, glassware, etc.), substituting laboratory reagent water or solid
for actual sample. The method blank must not contain any analytes above the
reported detection limit. The following common laboratory contaminants are
exceptions to this rule provided they are not present at greater than five
times the detection limit.
Volatiles
Methylene chloride
Toluene
2-Butanone
Acetone
Semi-volatiles
Dimethyl phthalate
Diethly phthalate
Di-n-butyl phthalate
Butyl benzyl phthalate
Bis (2-ethylhexyl) phthalate
Metals
Calcium
Magnesium
Sodium
A minimum of five percent (5%) of all laboratory analyses are laboratory
analytical method blanks.
Laboratory Analytical Method Check Sample Evaluations
Known concentrations of designated matrix spikes (actual analytical method
compounds) are added to a laboratory reagent blank prior to extraction and
analysis. Percent recovery determinations demonstrate the performance of the
analytical method. Failure of a check sample to meet established laboratory
recovery criteria is cause to stop the analysis until the problem is
resolved.
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ENSECQ-VWADSVWORTH/ALERT
Laboratories
QUALITY ASSURANCE I QUALITY CONTROL
PROGRAM SUMMARY
(cont'd)
At that time all associated samples must be re-analyzed. A minimum of five
percent (5%) of all laboratory analyses are laboratory analytical method
check samples.
Matrix Spike (MS)/Matrix Spike Duplicate (MSD) Recoverv Evaluations
Known concentrations of designated matrix spikes (actual analytical method
compounds) are added to two of three separate aliquots of a sequentially
predetermined sample prior to extraction and analysis. Percent recovery
determinations are calculated from both of the spiked samples by comparison
to the actual values generated from the unspiked sample. These percent
recovery determinations indicate the accuracy of the analysis at recovering
actual analytical method compounds from the matrix. Relative percent
difference determinations calculated from a comparison of the MS/MSD
recoveries demonstrate the precision of the analytical method. Actual
percent recovery and relative percent difference data is displayed alongside
their respective acceptable analytical method performance limits in the QA/QC
section of the report. The MS/MSD are considered in control when the
precision is within established control limits and the associated check
sample has been found to be acceptable. A minimum of ten percent (10%) of
all analyses are MS/MSD quality control samples.
**********************************EXAMPLE*********************************
COMPOUND SAMPLE MS MSD RPD QC LIMITS
CONC. %REC %REC RPD RECOVERY
4,4'-DDT 0 95 112 16 22 66-119
Benzene 10 86 93 8 20 39-150
(cmpd. name) sample 1st% 2nd% ReI. % accep. method
result recov. recov. diff. perform range
Analvtical Result Qualifiers
The following qualifiers, as defined below, may be appended to analytical
results in order to allow proper interpretation of the results presented:
J - indicates an estimated concentration (typically used when a dilution,
matrix interference or instrumental limitation prevents accurate quantitation
of a particular analyte).
B - indicates the presence of a particular analyte in the laboratory blank
analyzed concurrently with the samples. Results must be interpreted
accordingly.
OIL - indicates that because of matrix interferences and/or high analyte
concentrations, it was necessary to dilute the sample to a point where the
surrogate or spike concentrations fell below a quantifiable amount and could
not be reported.
I
I
liiiIifl ENSECO-WADSWORTH/ALERT
. Laboratories
I COMPANY : MISSIMER & ASSOCIATES,
LAB #: 3A2914-BK
MATRIX : WATER
I SAMPLE ID : LABORATORY BLANK
INC.
DATE RECEIVED:. 1/29/93
I
CERTIFICATION #: E84059
METALS ANALYTICAL REPORT HRS84297
SELECTED LIST
ITotal metals analysis results - as received
I
ELEMENT
I Chromium
Mercury
Nickel
I Lead
I
I
I
I
I
I
I NOTE: ND
(None Detected)
I
I
I
PREPARATION - DETECTION
ANALYSIS DATE RESULT LIMIT
2/ 9- 2/10/93 ND SO ug/L
2/ 9- 2/10/93 ND 2 ug/L
2/ 9- 2/10/93 ND SO ug/L
2/ 9- 2/10/93 ND 5 ug/L
I
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LAB ID
ELEMENT
ENSECO-VWADSVWORTH/ALERT
Laboratories
LCS
Chromium
Lead (furnace)
Mercury (vapor)
Nickel
MATRIX
WATER
LABORATORY CONTROL SAMPLE RESULTS
METALS
DATE DATE
PREPARED ANALYZED
02/09/93
02/09/93
02/09/93
02/09/93
02/10/93
02/10/93
02/10/93
02/10/93
LCS
%REC
QC LIMITS
RPD %REC
90
89
99
88
21 79-121
33 64-132
18 83-120
13 84-111
LCS
(~
I ~t
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Vi
WADSWORTH/ALERT Laboratories
Division of Enseco Incorporated
5910 Breckenridge Parkway, Suite H 813-621,0784
Tampa, FL 33610 FAX 813-623-6021
ANALYTICAL REPORT
TEI-904
08 JANUARY 1993
Presented to:
TOM TWITMYER
MISSIMER & ASSOCIATES, INC.
ENSECO-WADSWORTH/ALERT LABORATORIES
'~M!:!'~tn;+~
Project Manager
, 1993
A Corning Company
I
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I
I
I
I
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I
I
.
ENSECO-WADSVWORTH/ALERT
Laboratories
INVOLVEMENT
This report summarizes the analytical results of Project Number
TEI-904 submitted by Missimer & Associates, Inc. to Enseco-
Wadsworth/ALERT Laboratories who provided independent, analytical
services for this project under the direction of Tom Twitmyer. The
samples were accepted into Wadsworth's Florida facility on 08
January 1993, in accordance with documented sample acceptance
procedures. The associated analytical methods and sample results
are outlined sequentially in this report.
Analytical results included in this report have been reviewed for
compliance with the Laboratory QA/QC Plan as summarized in the
Quality Control section at the rear of the report. Sample custody
documentation describing the number of samples and sample matrices
is also included. Any qualifications and/or non-compliant items
have been noted below.
I
I
I
I
.
ENSECO-WADswom/ALERT
Laboratories
ANALYTICAL METHODS
Iwadsworth/ALERT Laboratories utilizes only USEPA approved analytical methods and
instrumentation. The analytical methods utilized for the analysis of these
samples are listed below.
IPARAMETER METHOD
---------------------------------------------------------------------------------
IVolatile organics
IIBase Neutral/Acid
Pesticides
IArsenic
Cadmium
Chromium
ILead
Mercury
Selenium
ISilver
Antimony
Beryllium
Copper
INickel
Thallium
Zinc
ITotal cyanide
Nitrate/Nitrite
IPhenolics
NOTE:
I{D)
EPA Methods
I
Std. Methods
IUSEPA Methods
SW846 Methods
I ASTM Methods
NIOSH Method
II
ORGANICS
** EPA Method 624
Extractables ** EPA Method 625
** EPA Method 608
METALS
** EPA Method 206.2
** EPA Method 200.7
** EPA Method 200.7
** EPA Method 239.2
** EPA Method 245.1
** EPA Method 270.2
** EPA Method 200.7
** EPA Method 200.7
** EPA Method 200.7
** EPA Method 200.7
** EPA Method 200.7
** EPA Method 279.2
** EPA Method 200.7
MISCELLANEOUS
** EPA Method 335.2
** EPA Method 353.3
** EPA Method 420.1
** Indicates usage of this method to obtain results for this
report.
Indicates draft version of this method was used
Methods for Chemical Analysis of Water and Wastes, USEPA, 600/4-
79-020, March, 1983. July, 1982
Drinking Waters USEPA, 600/4-88/039, December, 1988.
standard Methods for the Examination of Water and Waste-water,
APHA, 16th edition, 1985.
From 40CFR Part 136, published in Federal Register on October
26, 1984.
Test Methods for Evaluating Solid Waste Physical/Chemical
Methods, 3rd Edition, USEPA, 1986.
American society for Testing and Materials.
NIOSH Manual of Analytical Methods, National Insti tute for
occupational Safety and Health, 2nd Edition, April 1977.
I
I
.1 ENSECO-WADSVWORTH/ALERT
Laboratories
ICOMPANY: MISSIMER &: ASSOCIATES, INC.
LAB #: 3A0810-1
MATRIX: WATER
ISAMPLE ID: MW-1
DATE RECEIVED: '
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
NA
1/19/93
TE1-904
I
I
VOLATILE ORGANICS
USEPA METHOD 624 - GC/MS
CERTIFICATION #: E84059
BRS84297
IAcrolein
Acrylonitrile
IBenzene
Bromodichloromethane
Bromoform
IBromomethane
Carbon tetrachloride
IChlorobenzene
Chloroethane
IDibromoch1oromethane
1,2-Dich1orobenzene
1,3-Dich1orobenzene
11,4-Dich1orobenzene
. 1,1-Dich1oroethane
1,2-Dichloroethane
I
ND* 1,1-Dichloroethene ND
ND* 1,2-Dichloroethene(Total) ND
ND 1,2-Dichloropropane ND
ND cis-l,3-Dichloropropene ND
ND trans-l,3-Dich1oropropene ND
ND Ethy1benzene ND
ND Methylene chloride 2 B
ND 1,1,2,2-Tetrachloroethane ND
ND Tetrachloroethene ND
ND Toluene ND
ND 1, 1, 1-Trichloroethane ND
ND 1,1,2-Trichloroethane ND
ND Trich1oroethene ND
ND Trich1orof1uoromethane ND
ND Vinyl chloride ND
ND Xylene (Total) ND
ND
ND
12 -Ch1oroethylvinyl ether
Chloroform
Chloromethane
I NOTE:
I
I
SURROGATE
ND
ND*
ND**
J
B
(None Detected, lower detectable l~it = 1
(None Detected, lower detectable limit = 10
(None Detected, lower detectable limit =
(Detected, but below quantitation limit; est~ted
(Compound detected in method blank associated with
(Not Analyzed)
ug/L) as rec'd
ug/L) as rec'd
ug/L) as rec'd
value)
this sample)
RECOVERY:
%
ACCEPTABLE LIMITS
WATER SOLID
(7 5 - 123 ) ( 85 -12 6 )
(75-123) (89-124)
(86-115) (84-124)
LOW LEVEL
( 8 5 -13 8 )
(89-128)
(83-128)
11,2 -Dich1oroethane
To1uene-d8
Bromof1uorobenzene
I
102
106
105
I
I
III ENSECO-WADSVWO~/ALERT
Laboratones
ICOMPANY: MISSIMER & ASSOCIATES, INC.
~ #: 3A0810-1
MATRIX: WATER
lAMPLE ID: MW-1
DATE RECEIVED:
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/20/93
TEl-904
I
I
CERTIFICATION #: E84059
BASE/NEUTRAL -- EXTRACTABLE ORGANICS HRS84297
USEPA METHOD 625 - GC/MS (1 of 2)
~cenaPhthene
Acenaphthylene
(thracene
enzidine
Benzo (a) anthracene
lrenZO(b)f1Uoranthene
Benzo(k)fluoranthene
~enzo{ghi)perylene
renzo{a)pyrene
Bis(2-Ch1oroethoxy)methane
IBiS(2-ChloroethYl)ether
Bis(2-Ch1oroisopropyl) ether
ND
ND
ND
Dibenzo (a,h) antbracene
Di-n-butyl phthalate
1,2-Dichlorobenzene
ND
ND
ND
ND.
ND
ND
1,3-Dich1orobenzene
1,4-Dich1orobenzene
3,3'-Dichlorobenzidine
ND
ND
ND.
ND
ND
ND
Diethyl phthalate
D~ethyl phthalate
2,4-Dinitrotoluene
ND
ND
ND
ND
ND
ND
2,6-Dinitroto1uene
Di-n-octyl phthalate
Fluoranthene
ND
ND
ND
IBiS{2-EthYlheXY1)Phtha1ate
4-Bromopheny1 phenyl ether
Butyl benzyl phthalate
12 - Ch1oronaphthalene
4-Chlorophenyl phenyl
Chrysene
I
I
ND
ND
ND
Fluorene ND
Hexach1orobenzene ND
Hexachlorobutadiene ND
ND
ether ND
ND
Hexachlorocyclopentadiene ND
Hexachloroethane ND
Indeno(1,2,3-cd)pyrene ND
I
I
I
ND
ND*
J
B
(None Detected, lower detectable limit = 10
(None Detected, lower detectable l~it = 50
(Detected, but below quantitation l~it; estimated
(Compound detected in method blank associated with
(Not Analyzed)
ug/L) as rec'd
ug/L) as rec'd
value)
this sample)
INOTE:
.1 ENSECO-WADSWORTH/ALERT
Laboratories
ICOMPANY: MISSIMER &: ASSOCIATES, INC.
LAB #: 3A0810-1
MATRIX: WATER
ISAMPLE ID: MW-1
I
I
DATE RECEIVED:
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/20/93
TE1.-904
CERTIPICATION #: E840S9
BASE/NEUTRAL EXTRACTABLE ORGANICS BRS84297
USEPA METHOD 625 - GC/MS (2 of 2)
I
I
IIsoPhorone
Naphthalene
Nitrobenzene
IIN-Nitrosod~ethYlamine
N-Nitrosodiphenylamine
N-Nitrosodi-n-propy1amine
I Phenan threne
pyrene
11, 2 , 4 - Trichlorobenzene
I
I
I
I
I
I NOTE: ND
ND*
J
I B
ND
ND
ND
ND
ND
ND
ND
ND
ND
(None Detected, lower detectable l~it = 10 ug/L) as rec'd
(None Detected, lower detectable l~it = 50 ug/L) as rec'd
(Detected, but below quantitation limit: estimated value)
(Compound detected in method blank associated with this sample)
(Not Analyzed)
I SURROGATE RECOVERY:
Nitrobenzene-dS
Fluorobiphenyl
I Terphenyl- d1.4
%
ACCEPTABLE LIMITS
WATER SOLID
(22-1.35) (1.0-1.55)
(34 -140) (12 -153)
(10-132) (13-140)
98
97
53
I
I
TiIiiilI ENSECO-WADSWORTH/ALERT
. Laboratories
ICOMPANY: MISSIMER & ASSOCIATES, INC.
LAB #: 3A0810-1
MATRIX: WATER
ISAMPLE ID: MW-1
TEl-904
DATE RECEIVED: .
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/20/93
ACID EXTRACTABLE ORGANICS
USEPA METHOD 625 - GC/MS
CERTIFICATION #: E84059
BRS84297
I
I
14-Chloro-3-methYlPhenOl
2-Chloropheno1
12,4-DichloroPhenol
2,4-Dimethy1phenol
2,4-Dinitrophenol
12-MethYl-4,6-dinitroPhenol
2-Nitrophenol
14 -Ni trophenol
Pentachlorophenol
Phenol
12,4,6-Trich1oroPhenol
I
I
I
I
INOTE: ND
ND*
J
I B
ND
ND
ND
ND
ND*
ND*
ND
ND*
ND*
ND
ND
(None Detected, lower detectable limit = 10
(None Detected, lower detectable limit · 50
(Detected, but below quantitation limit; estimated
(Compound detected in method blank associated with
(Not Analyzed)
ug/L) as rec'd
ug/L) as rec'd
value)
this sample)
I SURROGATE RECOVERY:
2-F1uorophenol
Phenol-d5
12,4,6 -Tribromophenol
"
74
76
75
ACCEPTABLE LDKITS
WATER SOLID
(17-95) (24-118)
(11-89) (17-124)
(10-134) (10-156)
I
I
. ENSECO-VWADSVWORTH/ALERT
Labaratories
ICOMPANY: MISSIMER &: ASSOCIATES, INC.
LAB #: 3A0810-1
MATRIX: WATER
ISAMPLE ID: MW-1
TEl-904
I
I
I
II 1-Methylnaphthalene
2-Methylnaphthalene
I
I
I
DATE RECEIVED: .
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/20/93
CERTIFICATION #: E84059
BRS84297
SELECTED ORGANIC COMPOUNDS ANALYTICAL REPORT
PARAMETER
RESULT (ug /L )
ND
ND
DETECTION
LIMIT
5
5
INOTE:
ND
J
(None Detected) as rec'd
(Detected, but below quantitation limit; estimated value)
ACCEPTABLE LIMITS
WATER SOLID
ISURROGATE RECOVERY:
Nitrobenzene-d5
12-FluorobiPhenYl
Terphenyl-d14
(22-135)
(34-140)
( 10 -132 )
I
I
I
I
I
(10-155)
(12 -153)
(13 -140)
%
98
97
53
I
I
fill ENSECO-WADSVWORTH/ALERT
. Laboratories
.COMPANY: MISSIMER &: ASSOCIATES, INC.
IILAB #: 3A0810-1
MATRIX: WATER
LAMPLE ID: MW-1
DATE RECEIVED: ,
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/13/93
TEl-904
CERTIPlCATION #: E84059
CHLORINATED PESTICIDES BRS84297
ME'l'IIOD 608 LIST - GC
I
I
I
4,4'-DDT
ICh10rdane
Toxaphene
RESULT (ug/L ) DETECTION LIMIT
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 1
ND 4
E1Pha - BHC
eta-BHC
elta-BHC
~indane
.eptachlor
Aldrin
IHeptach10r Epoxide
Endosulfan I
IDieldrin
4,4'-DDE
Endrin
IEndosu1fan II
4,4'-DDD
IEndrin Aldehyde
Endosulfan Sulfate
I
INOTE: ND
(None Detected) as rec'd
(Not Analyzed)
ISURROGATE RECOVERY:
Tetrachloro(m)xylene
I Dibutylchlorendate
%
ACCEPTABLE
WATER
(33 -122)
(18-129)
LIMITS
SOLID
(32-154)
(27 -139 )
61
52
I
I
I . ENSECO-WADSVWORTH/ALERT
Laboratories
~OMPANY : MISSIMER & ASSOCIATES, INC.
LAB #: 3A0810-1
CTRIX: WATER
AMPLE ID: MW-1 TEl-904
DATE RECEIVED: '
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/13/93
I
I
CERTIFICATION #: E84059
POLYCHLORINATED BIPHENYLS BRS84297
METHOD 608 LIST - GC
tCB-1016
CB-1221
PCB-1232
ICB-1242
PCB-1248
(CB-1254
CB-1260
ND
ND
ND
ND
ND
ND
ND
I
I
I
I
I
I
NOTE:
I
ND
ND*
(None Detected, lower detectable l~it = 1
(None Detected, lower detectable l~it =
(Not Analyzed)
ug/L) as rec'd
ug/L) as rec'd
SURROGATE RECOVERY:
I Tetrachloro (m) xylene
%
ACCEPTABLE LLKITS
WATER SOLID
(33-122) (32-154)
61
I
I
I
I
IF ENSECO-WADSVWORTH/ALERT
. Laboratories
~OMPANY : MISSIMER & ASSOCIATES, INC.
-r:AB #: 3A0810-1
MATRIX : WATER
LAMPLE ID : MW-1
DATE RECEIVED: , 1/ 8/93
TEl-904
I
CERTIFICATION #: E84059
METALS ANALYTICAL REPORT HRS84297
SELECTED LIST
lFota1 metals analysis results - as received
I
ELEMENT
ISi1ver
Arsenic
Beryllium
!cadmium
Chromium
Icopper
Mercury
.:rickel
.Lead
Antimony
Ise1enium
Thallium
IZinc
PREPARATION - DETECTION
ANALYSIS DATE RESULT LIMIT
1/11/93 ND 50 ug/L
1/11/93 29 10 ug/L
1/11/93 ND 50 ug/L
1/11/93 ND 10 ug/L
1/11/93 540 50 ug/L
1/11/93 230 50 ug/L
1/12/93 3 2 ug/L
1/11/93 72 50 ug/L
1/11- 1/12/93 24 5 ug/L
1/11- 1/12/93 ND 300 ug/L
1/11/93 8 5 ug/L
1/11- 1/12/93 ND 10 ug/L
1/11/93 98 50 ug/L
I
I
INOTE: ND
(None Detected)
I
I
I
I
I
.1 ENSECO-WADSVWORTH/ALERT
Laboratories
ICOMPANY: MISSIMER & ASSOCIATES, INC.
LAB #: 3A0810-1
MATRIX : WATER
ISAMPLE ID : MW-1
TEl-904
I
I
ANALYTICAL REPORT
DATE RECEIVED: , 1/ 8/93
CERTIFICATION #: E84059
HRS84297
I PARAMETER
Cyanide
~itrate-Nitrite Nitrogen
-Total Recoverable Phenolics
I
I
I
I
I
I
I
INOTE:
(None Detected)
ND
I
I
I
PREPARATION -
ANALYSIS DATE
1/19/93
1/14/93
1/14/93
RESULT
DETECTION
LIMIT
ND
16
ND
0.005
2.5
0.05
mg/L
mg/L
mg/L
I
I
.1 ENSECO-WADSVWORTH/ALERT
Laboratories
ICOMPANY: MISSIMER
LAB #: 3A0810-2
MATRIX: WATER
!sAMPLE ID: MW- 2
& ASSOCIATES, INC.
DATE RECEIVED: ,
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
NA
1/12/93
TEl-904
I
I
CERTIFICATION #: E84059
VOLATILE ORGANICS HRS84297
USEPA METHOD 624 - GC/MS
~crolein ND* 1,1-Dichloroethene ND
Acrylonitrile ND* 1,2-Dichloroethene(Total) ND
(enzene ND 1,2-Dichloropropane ND
: romodich1oromethane ND cis-1,3-Dich1oropropene ND
Bromoform ND trans-1,3-Dichloropropene ND
rromomethane ND Ethy1benzene ND
Carbon tetrachloride ND Methylene chloride ND
IChlorobenzene ND 1, 1, 2, 2-Tetrachloroethane ND
Chloroethane ND Tetrachloroethene ND
2-Chloroethylvinyl ether ND Toluene ND
IChloroform ND 1,1,1-Trichloroethane ND
Chloromethane ND 1,1,2-Trichloroethane ND
IDibromochloromethane ND Trich1oroethene ND
1,2-Dich1orobenzene ND Trich1orof1uoromethane ND
1,3-Dichlorobenzene ND Vinyl chloride ND
11,4-Dichlorobenzene ND Xylene (Total) ND
1,1-Dichloroethane ND
1,2-Dich1oroethane ND
I
INOTE:
ND
ND*
ND**
J
B
{None Detected, lower detectable l~it = 1
(None Detected, lower detectable limit = 10
(None Detected, lower detectable limit =
(Detected, but below quantitation limit; estimated
(Compound detected in method blank associated with
(Not Analyzed)
ug/L) as rec'd
ug/L) as rec'd
ug/L) as rec'd
value)
this sample)
I
I
SURROGATE
RECOVERY:
"
ACCEPTABLE LIMITS
WATER SOLID
(75-123) (85-126)
(75-123) (89-124)
(86-115) (84-124)
LOW LEVEL
(85-138)
(89-128)
(83 -128)
11, 2 - Dich1oroethane
Toluene-d8
Bromofluorobenzene
I
91
94
93
I
I
.111 ENSECO-WADSVWO.RTH/ALERT
Laboratones
~OMPANY: MISSIMER & ASSOCIATES, INC.
':AB #: 3A0810-2
MATRIX: WATER
IAMPLE ID: MW - 2
DATE RECEIVED:
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/20/93
TEl-904
I
I
CERTIFICATION #: E84059
BASE/NEUTRAL - - EXTRACTABLE ORGANICS HRS84297
USEPA METHOD 625 - GC/MS (1 of 2)
lcenaPhthene
Acenaphthylene
(thracene
enzidine
Benzo{a)anthracene
!renZO(b)flUoranthene
Benzo(k)fluoranthene
lPenzo(ghi)perylene
Fenzo(a)pyrene
NO
NO
NO
Dibenzo (a,h) anthracene
Di-n-butyl phthalate
1,2-Dichlorobenzene
NO
NO
NO
NO*
ND
NO
1,3-Dich1orobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
NO
NO
NO*
NO
ND
NO
Diethyl phthalate
Dimethyl phthalate
2,4-Dinitrotoluene
NO
NO
NO
~iS(2-Chloroethoxy)methane NO
is (2-Chloroethyl) ether NO
is (2-Chloroisopropyl) ether NO
2,6-Dinitrotoluene NO
Di-n-octyl phthalate NO
Fluoranthene NO
~is(2-Ethy1hexy1)phtha1ate
~-Bromopheny1 phenyl ether
Butyl benzyl phthalate
IE-Ch1oronaPhtha1ene
4-Chloropheny1 phenyl
Chrysene
I
ND
ND
ND
Fluorene NO
Hexachlorobenzene NO
Hexachlorobutadiene NO
NO
ether ND
NO
Hexach1orocyclopentadiene NO
Hexachloroethane NO
Indeno (1, 2, 3-cd)pyrene NO
I
I
I
I
NO
NO*
J
B
(None Detected, lower detectable limit = 10 ug/L) as rec'd
(None Detected, lower detectable limit = 50 ug/L) as rec'd
(Detected, but below quantitation limit; estimated value)
(Compound detected in method blank associated with this sample)
(Not Analyzed)
tOTE:
I
I
.1 ENSECO-VWADSWORTH/ALERT
Laboratories
~OMPANY: MISSIMER &: ASSOCIATES, INC.
IILAB #: 3A0810-2
MATRIX: WATER
LAMPLE ID: MW - 2
DATE RECEIVED:
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/20/93
TEl-904
I
I
CERTIFICATION #: E84059
BASE/NEUTRAL EXTRACTABLE ORGANICS BRS84297
USEPA METHOD 625 - GC/MS (2 of 2)
~sophorone
ataphthalene
Nitrobenzene
~-Nitrosodimethy1amine
~-Nitrosodiphenylamine
N-Nitrosodi-n-propylamine
Iphenanthrene
Pyrene
11, 2, 4-Trichlorobenzene
NO
NO
NO
ND
NO
NO
NO
ND
NO
I
I
I
I
I
INOTE: NO
NO*
J
I B
(None Detected, lower detectable limit = 10
(None Detected, lower detectable limit · 50
(Detected, but below quantitation limit: estimated
(Compound detected in method blank associated with
(Not Analyzed)
ug/L) as rec'd
ug/L) as rec'd
value)
this sample)
I SURROGATE RECOVERY:
Nitrobenzene-d5
F1uorobiphenyl
I Terphenyl- d14
%
ACCEPTABLE Lr.HITS
WATER SOLID
(22-135) (10-155)
(34 -140) (12 -153)
(10-132) (13-140)
100
97
73
I
I
. ENSECO-VWADSWOm/ALERT
Laboratories
.COMPANY: MISSIMER << ASSOCIATES, INC.
IILiB #: 3A0810-2
MATRIX: WATER
LAMPLE ID: MW- 2
DATE RECEIVED: .
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/20/93
TE1-904
I
I
ACID EXTRACTABLE ORGANICS
USEPA METHOD 625 - GC/MS
CERTIFICATION #: E84059
BRS84297
14-Ch1oro-3-methY1PhenOl
2-Chlorophenol
1[,4-DichloroPhenol
2,4-Dimethylphenol
2,4-Dinitropheno1
12-MethYl-4,6-dinitroPheno1
2-Nitrophenol
14-NitroPhenol
Pentachlorophenol
ND
ND
ND
ND
ND*
ND*
ND
ND*
ND*
Phenol
12,4,6-TrichloroPhenol
ND
ND
I.
I
1
I
I
ND
ND*
J
B
(None Detected, lower detectable l~it . 10
(None Detected, lower detectable l~it . 50
(Detected, but below quantitation l~itJ est~ted
{Compound detected in method blank associated with
(Not Analyzed)
ug/L) as rec'd
ug/L) as rec'd
value)
this sample)
INOTE:
I SURROGATE RECOVERY:
2-F1uorophenol
Phenol-d5
12,4,6 -Tribromophenol
"
ACCEPTABLE LIMITS
WATER SOLID
(17-95) (24-118)
(11-89) (17-124)
(10-134) (10-156)
78
84
80
I
I
DATE RECEIVED: .
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/20/93
TEl-904
I
I
I
11-MethYlnaPhthalene
2-Methylnaphthalene
I
I
I
I
I
I
CERTIFICATION #: E84059
HRS84297
SELECTED ORGANIC COMPOUNDS ANALYTICAL REPORT
PARAMETER
RESULT (ug /L )
DETECTION
LIMIT
ND
ND
5
5
INOTE: ND
J
I SURROGATE
(None Detected) as rec'd
(Detected, but below quantitation limit; estimated value)
RECOVERY:
ACCEPTABLE LIMITS
WATER SOLID
%
I Ni trobenzene - d5
2-Fluorobiphenyl
Terphenyl-d14
I
I
(22-135)
(34 -140)
(10-132)
(10-155)
(12 -153)
(13 -140)
100
97
73
I
I
. ENSECO-WADSWOm/ALERT
Laboratories
ICOMPANY: MISSIMER & ASSOCIATES, INC.
LAB #: 3A0810-2
MATRIX: WATER
ISAMPLE ID: MW-2
DATE RECEIVED: '
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/13/93
TEl-904
I
I
I
CERTIFICATION #: E84059
CHLORINATED PESTICIDES HRS84297
METHOD 608 LIST - GC
ILindane
Heptachlor
Aldrin
IHeptachlor Epoxide
Endosulfan I
IDieldrin
4,4'-DDE
Endrin
IEndosu1fan II
4,4'-DDD
Endrin Aldehyde
IEndosulfan Sulfate
4,4'-DDT
IChlordane
Toxaphene
RESULT (ug/L ) DETECTION LIMIT
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 0.1
ND 1
ND 4
Alpha-BHC
IBeta-BHC
Delta-BHC
I
INOTE: ND
(None Detected) as rec'd
(Not Analyzed)
I SURROGATE RECOVERY:
Tetrachloro(m)xylene
I Dibu tylchlorenda te
"
ACCEPTABLE
WATER
(33-122)
(18-129)
LIMITS
SOLID
(32-154)
(27 -139)
46
17
I
I
I
. ENSECO-WADSWORTH/ALERT
Laboratories
ICOMPANY : MISSIMER & ASSOCIATES, INC.
LAB #: 3A0810-2
MATRIX: WATER
ISAMPLE ID: MW-2
DATE RECEIVED: '
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/13/93
TEJ.-904
I
I
CERTIPlCATION #: E84059
POLYCHLORINATED BIPHENYLS HRS84297
I1ETHOD 608 LIST - GC
IPCB-1016
PCB-1221
PCB-1232
IpCB-1242
PCB-1248
PCB-1254
IpCB-1260
ND
ND
ND
ND
ND
ND
ND
I
I
I
I
I
I
NOTE:
I
ND
ND*
(None Detected, lower detectable limit = 1
(None Detected, lower detectable limit =
(Not Analyzed)
ug/L) as rec'd
ug/L) as rec'd
SURROGATE RECOVERY:
I Tetrachloro (m) xylene
%
ACCEPTABLE LIMITS
WATER SOLID
(33-122) (32-154)
46
I
I
I
I
. ENSECO-VWADSWORTH/ALERT
Laboratories
lboMPANY : MISSIMER & ASSOCIATES, INC.
~ #: 3A0810-2
MATRIX : WATER
~AMPLE ID : MN-2 TEl-904
DATE RECEIVED: 1/ 8/93
I
CERTIFICATION #: E84059
METALS ANALYTICAL REPORT HRS84297
SELECTED LIST
lFota1 metals analysis results - as received
I ELEMENT
aal ver
IlA;;senic
Beryllium
ladmium
Chromium
ropper
Iz.tercury
Nickel
tead
Antimony
.e1enium
Fha1lium
IZinc
PREPARATION - DETECTION
ANALYSIS DATE RESULT LIMIT
1/11/93 ND 50 ug/L
1/11/93 20 10 ug/L
1/11/93 ND 50 ug/L
1/11/93 ND 10 ug/L
1/11/93 450 50 ug/L
1/11/93 95 50 ug/L
1/12/93 6 2 ug/L
1/11/93 110 50 ug/L
1/11- 1/12/93 250 40 ug/L
1/11- 1/12/93 ND 300 ug/L
1/11/93 7 5 ug/L
1/11- 1/12/93' ND 10 ug/L
1/11/93 72 50 ug/L
I
I
rOTE:
ND
(None Detected)
I
I
I
I
I
. ENSECO-WADSWORTH/ALERT
Laboratories
ICOMPANY : MISSIMER
LAB #: 3A0810-2
MATRIX : WATER
ISAMPLE ID : MW-2
& ASSOCIATES, INC.
I
I
I PARAMETER
Cyanide
INitrate-Nitrite Nitrogen
Total Recoverable Phenolics
TEl-904
ANALYTICAL REPORT
DATE RECEIVED: 1/ 8/93
CERTIFICATION #: E84059
BRS84297
I
I
I
I
I
I
I
NOTE: ND
I
I
I
I
(None Detected)
PREPARATION -
ANALYSIS DATE
1/19/93
1/14/93
1/14/93
RESULT
DETECTION
LIMIT
ND
13
ND
0.005
2.5
0.05
mg/L
mg/L
mg/L
I
I
r.r.r.r EIISEClI-WADSWIIIIlIIIAISIT
. Laboratories
1 COMPANY : MISSIMER & ASSOCIATES, INC.
LAB #: 3A0810-3
MATRIX: WATER
ISAMPLE ID: MN-3
DATE RECEIVED: .
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
NA
1/12/93
TEl-904
I
I
CERTIFICATION #: E84059
VOLATILE ORGANICS BRS84297
USEPA METHOD 624 - GC/MS
IAcrolein
Acrylonitrile
IBenzene
Bromodich1oromethane
Bromoform
IBromomethane
Carbon tetrachloride
IChlorobenzene
Chloroethane
IDibromochloromethane
1,2-Dichlorobenzene
1,3-Dich1orobenzene
11,4 -Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1
ND. 1,1-Dichloroethene ND
ND. 1, 2-Dichloroethene (Total) ND
ND 1,2-Dichloropropane ND
NO cis-1,3-Dich1oropropene ND
ND trans-1,3-Dich1oropropene ND
ND Ethy1benzene ND
NO Methylene chloride ND
NO 1, 1, 2, 2-Tetrachloroethane ND
NO Tetrachloroethene ND
NO Toluene ND
NO 1, 1, 1-Trichloroethane ND
NO 1, 1, 2-Trichloroethane ND
NO Trich1oroethene ND
NO Trichlorof1uoromethane ND
NO Vinyl chloride ND
NO Xylene (Total) ND
NO
ND
12-ChloroethY1VinYl ether
Chloroform
Chloromethane
.INOTE:
I
I
SURROGATE
ND
ND.
ND..
J
B
(None Detected, lower detectable limit = 1
(None Detected, lower detectable l~it = 10
{None Detected, lower detectable limit =
{Detected, but below quantitation limit; estimated
(Compound detected in method blank associated with
(Not Analyzed)
ug/L} as rec'd
ug/L) as rec'd
ug/L} as rec'd
value)
this sample)
RECOVERY:
%
ACCEPTABLE LIMITS
WATER SOLID
(75-123) (85-126)
(75-123) (89-124)
(86-115) (84-124)
LOW LEVEL
{85-138}
(89-128)
(83 -128)
11,2-Dich1oroethane
To1uene-d8
Bromofluorobenzene
I
97
100
93
.1 ENSECO-WADSWORTH/ALERT
Laboratories
IbOMPANY: MISSIMER & ASSOCIATES, INC.
-.LiB #: 3A0810-3
MATRIX: WATER
LAMPLE ID: MW- 3
I
I
DATE RECBIVED: .
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/20/93
TEl-904
I
I
CERTIFICATION #: B84059
BASE/NEUTRAL -- EXTRACTABLE ORGANICS HRS84297
USEPA METHOD 625 - GC/MS (1 of 2)
lcenaPhthene
Acenaphthylene
,~thracene
~enzidine
Benzo(a)anthracene
!renZO(b)f1Uoranthene
Benzo(k)fluoranthene
~enzo(ghi)perylene
penzo(a)pyrene
ND
ND
ND
Dibenzo (a,h) anthracene
Di-n-butyl phthalate
1,2-Dichlorobenzene
ND
ND
ND
ND*
ND
ND
1,3-Dich1orobenzene
1,4-Dich1orobenzene
3,3'-Dich1orobenzidine
ND
ND
ND*
ND
ND
ND
Diethy1 phthalate
D~ethyl phthalate
2,4-Dinitrotoluene
ND
ND
ND
Bis(2-Chloroethoxy)methane NO
lmis(2-Chloroethyl)ether ND
~is(2-Chloroisopropyl)ether ND
2,6-Dinitrotoluene ND
Di-n-octyl phthalate ND
Fluoranthene ND
~is(2-Ethy1hexy1)phtha1ate
~-Bromopheny1 phenyl ether
Butyl benzyl phthalate
IE-ChloronaPhthalene
~-Chlorophenyl phenyl
Chrysene
I
ND
ND
ND
Fluorene ND
Hexach1orobenzene ND
Hexachlorobutadiene ND
ND
ether ND
ND
Hexachlorocyc1opentadiene ND
Hexachloroethane ND
Indeno (1, 2, 3-cd)pyrene ND
I
tOTE:
ND
ND*
J
B
(None Detected, lower detectable limit = 10
(None Detected, lower detectable limit = 50
(Detected, but below quantitation limit; estimated
(Compound detected in method blank associated with
(Not Analyzed)
ug/L) as rec'd
ug/L) as rec'd
value)
this sample)
I
I
I
I
I
DATE RECEIVED:
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/20/93
TEl-904
I
I
CERTIFICATION #: E84059
BASE/NEUTRAL EXTRACTABLE ORGANICS BRS84297
USEPA METHOD 625 - GC/JIIS (2 of 2)
.~sophorone
Faphthalene
Nitrobenzene
t-NitrosodimethYlamine
-Nitrosodiphenylamine
N-Nitrosodi-n-propylamine
Iphenanthrene
Pyrene
11, 2, 4-Trichlorobenzene
NO
NO
NO
NO
ND
ND
NO
NO
NO
I
I
I
I
I
INOTE: NO
NO*
J
I B
(None Detected, lower detectable l~it . 10
(None Detected, lower detectable l~it . 50
(Detected, but below quantitation l~it: estimated
(Compound detected in method blank associated with
(Not Analyzed)
ug/L) as rec'd
ug/L) as rec'd
value)
this sample)
I SURROGATE RECOVERY:
Nitrobenzene-d5
F1uorobiphenyl
I Terphenyl- d14
%
ACCEPTABLE LIMITS
WATER SOLID
(22-135) (10-155)
(34-140) (12-153)
(10-132) (13-140)
95
98
50
I
I
TEl-904
DATE RECEIVED: ,
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/20/93
ACID EXTRACTABLE ORGANICS
USEPA METHOD 625 - GC/MS
CERTIPICATION #: E84059
BRS84297
I
I
~-Chloro-3-methYlPhenOl
2-Chlorophenol
.r,4-Dich1orophenol
~,4-DimethY1Phen01
2,4-Dinitrophenol
IF-MethYl-4,6-dinitroPhenol
2-Nitrophenol
.4-Nitrophenol
Fentach1orophenol
.!henol
12,4,6-Trichlorophenol
I
I
I
I
tOTE: ND
ND*
J
I B
ND
ND
ND
ND
ND*
ND*
ND
ND*
ND*
ND
ND
{None Detected, lower detectable limit . 10
{None Detected, lower detectable limit . 50
{Detected, but below quantitation limit; estimated
{Compound detected in method blank associated with
(Not Analyzed)
ISURROGATE RECOVERY:
2-P1uoropheno1
Phenol-d5
12,4,6-TribromoPhenol
%
77
80
77
ACCEPTABLE LIMITS
WATER SOLID
(17-95) (24-118)
(11-89) (17-124)
(10-134) (10-156)
ug/L) as rec'd
ug/L) as rec'd
value)
this sample)
I
I
. ENSECO-WADSWORTH/ALERT
Laboratories
I COMPANY: MISSIMER &: ASSOCIATES, INC.
LAB #: 3A0810-3
MATRIX: WATER
I SAMPLE ID: MW-3
TE~-904
I
I
I
:1
I
I
I
I
I
I
DATE RECEIVED: .
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/20/93
CERTIFICATION #: E84059
HRS84297
SELECTED ORGANIC COMPOUNDS ANALYTICAL REPORT
PARAMETER
1-Methylnaphthalene
2-Methylnaphthalene
I NOTE: NO
J
I SURROGATE
RESULT (ug /L )
NO
NO
(None Detected) as rec'd
(Detected, but below quantitation limit; estimated value)
RECOVERY:
ACCEPTABLE LIMITS
WATER SOLID
I Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d14
I
I
(22-135)
(34-140)
(10-132)
(~0-155)
(12-153)
(13 -140)
DETECTION
LIMIT
5
5
%
95
98
50
I
I
~ EllSECO-WADSWORlH/AlBIT
. Laboratories
ICOMPANY: MISSIMER & ASSOCIATES, INC.
LAB #: 3A0810-3
MATRIX: WATER
ISAMPLE ID: )lW-3
DATE RECEIVED: ,
DATE EXTRACTED:
DATB ANALYZED:
1/ 8/93
1/11/93
1/13/93
TEl-904
I
I
I
CHLORINATED PESTICIDES
METHOD 608 LIST - GC
CERTIFICATION #: B84059
HRS84297
ILindane
Heptachlor
Aldrin
IHeptachlor Epoxide
Endosulfan I
Dieldrin
14, 4' - DDE
Endrin
IEndosulfan II
4,4'-DDD
Endrin,Aldehyde
IEndosulfan Sulfate
4,4'-DDT
ICh10rdane
Toxaphene
RESULT (ug/L ) DETECTION LIMIT
NO 0.1
NO 0.1
NO 0.1
ND 0.1
NO 0.1
NO 0.1
NO 0.1
NO 0.1
NO 0.1
NO 0.1
NO 0.1
NO 0.1
NO 0.1
NO 0.1
NO 0.1
ND 0.1
NO 1
NO 4
Alpha-BHC
IBeta-BHC
Delta-BHC
I
INOTE:
NO
(None Detected) as rec'd
(Not Analyzed)
I SURROGATE RECOVERY:
Tetrach1oro(m)xy1ene
Dibutylchlorendate
I
I
%
ACCEPTABLE
WATER
(33-122)
(18-129)
LIMITS
SOLID
(32-154)
(27 -139 )
61
22
I
I
. ENSECO-VWADSVWORTH/ALERT
Laboratories
ICOMPANY : MISSIMER &: ASSOCIATES, INC.
LAB I: 3A0810-3
MATRIX: WATER
IS~LE ID: MW-3
DATE RECEIVED: '
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/13/93
TEl-904
CERTIFICATION I: E84059
POLYCHLORINATED BIPHENYLS HRS84297
METHOD 608 LIST - GC
I
I
IPCB-1016
PCB-1221
PCB-1232
IpCB-1242
PCB-1248
PCB-1254
IpCB-1260
ND
ND
ND
ND
ND
ND
ND
I
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I
NOTE:
I
ND
ND*
(None Detected, lower detectable limit = 1
(None Detected, lower detectable l~it =
(Not Analyzed)
ug/L) as rec'd
ug/L) as rec'd
SURROGATE RECOVERY:
III Tetrachloro (m)xylene
%
ACCEPTABLE LIMITS
WATER SOLID
(33-122) (32-154)
61
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-
I
I . ENSECO-VWADSVWORTH/ALERT
Laboratories
~OMPANY : MISSIMER & ASSOCIATES, INC.
LAB #: 3A0810-3
~TRIX : WATER
~AMPLE ID : MW-3 TEl-904
DATE RECEIVED: ' 1/ 8/93
I
CERTIFICATION #: E840s9
METALS ANALYTICAL REPORT HRS84~97
SELECTED LIST
~ota1 metals analysis results - as received
I
rinC
PREPARATION - DETECTION
ANALYSIS DATE RESULT LIMIT
1/11/93 ND 50 ug/L
1/11/93 16 10 ug/L
1/11/93 ND 50 ug/L
1/11/93 ND 10 ug/L
1/11/93 270 50 ug/L
1/11/93 73 50 ug/L
1/12/93 3 2 ug/L
1/11/93 50 50 ug/L
1/11- 1/12/93 95 20 ug/L
1/11- 1/12/93 ND 300 ug/L
1/11/93 ND 5 ug/L
1/11- 1/12/93 ND 10 ug/L
1/11/93 84 SO ug/L
ELEMENT
lil ver
Arsenic
~ery1lium
~admium
Chromium
fopper
Mercury
.ickel
..ead
Etimony
e1enium
hal1ium
I
I
JOTE: ND
(None Detected)
I
I
I
I
I ii ENSECO-WADSVWORTH/ALERT
Laboratories
ICOMPANY : MISSIMER & ASSOCIATES, INC.
LAB #: 3A0810-3
CTRIX : WATER
SAMPLE ID : MW-3 TEl-904
I
I
ANALYTICAL REPORT
DATE RECEIVED: ' 1/ 8/93
CERTIFICATION #: E84059
BRS84297
I PAR.AMETER
lICyanide
~itrate-Nitrite Nitrogen
Total Recoverable Phenolics
I
I
I
I
I
I
I
INOTE:
ND
(None Detected)
I
I
I
PREPARATION -
ANALYSIS DATB
1/19/93
1./1.4/93
1./1.4/93
RESOLT
DETECTION
LIMIT
0.01
0.56
ND
0.005
0.05
0.05
mg/L
mg/L
mg/L
I
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.
ENSECD-VWADSVWORTH/ALERT
Laboratories
QUALITY CONTROL SECTION
. Quality Control Summary
. Laboratory Blanks
. Laboratory Control Sample
. Matrix Spike/Matrix Spike Duplicate Results
. Sample Custody Documentation
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.
ENSECO-\MADS\MORTH/ALERT
Laboratories
QUALITY ASSURANCE / QUALITY CONTROL
PROGRAM SUMMARY
Wadsworth/ ALERT Laboratories considers continuous analytical method
performance evaluations to be an integral portion of the data package, and
routinely includes the pertinent QA/QC data associated with various
analytical result reports. Brief discussions of the various QA/QC procedures
utilized to measure acceptable method and matrix performance follow.
Surroqate Spike Recovery Evaluations
Known concentrations of designated surrogate spikes, consisting of a number
of similar, non-method compounds or method compound analogues, are added, as
appropriate, to routine GC and GC/MS sample fractions prior to extraction and
analysis. The percent recovery determinations calculated from the subsequent
analysis is an indication of the overall method efficiency for the individual
sample. This surrogate spike recovery data is displayed alongside acceptable
analytical method performance limits at the bottom of each applicable
analytical result report sheet.
NOTE: Acceptable method performance for Base/Neutral Acid extractables is
indicated by two (2) of three (3) surrogates for each fraction with a minimum
recovery of ten (10) percent each. For Pesticides one (1) of two (2)
surrogates meeting performance criteria is acceptable.
Laboratory Analytical Method Blank Evaluations
Laboratory analytical method blanks are systematically prepared and analyzed
in order to continuously evaluate the system interferences and background
contamination levels associated with each analytical method. These method
blanks include all aspects of actual laboratory method analysis (chemical
reagents, glassware, etc.), substituting laboratory reagent water or solid
for actual sample. The method blank must not contain any analytes above the
reported detection limit. The following common laboratory contaminants are
exceptions to this rule provided they are not present at greater than five
times the detection limit.
Volatiles
Methylene chloride
Toluene
2-Butanone
Acetone
Semi-volatiles
Dimethyl phthalate
Diethly phthalate
Di-n-butyl phthalate
Butyl benzyl phthalate
Bis (2-ethylhexyl) phthalate
Metals
Calcium
Magnesium
Sodium
A minimum of five percent (5%) of all laboratory analyses are laboratory
analytical method blanks.
Laboratory Analytical Method Check Sample Evaluations
Known concentrations of designated matrix spikes (actual analytical method
compounds) are added to a laboratory reagent blank prior to extraction and
analysis. Percent recovery determinations demonstrate the performance of the
analytical method. Failure of a check sample to meet established laboratory
recovery criteria is cause to stop the analysis until the problem is
resolved.
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ENSECO-VWADSVWORTH/ALERT
Laboratories
QUALITY
ASSURANCE / QUALITY CONTROL
PROGRAM SUMMARY
(cont'd)
At that time all associated samples must be re-analyzed. A minimum of five
percent (5%) of all laboratory analyses are laboratory analytical method
check samples.
Matrix Spike (MS)/Matrix Spike Duplicate (MSD) Recovery Evaluations
Known concentrations of designated matrix spikes (actual analytical method
compounds) are added to two of three separate aliquots of a sequentially
predetermined sample prior to extraction and analysis. Percent recovery
determinations are calculated from both of the spiked samples by comparison
to the actual values generated from the unspiked sample. These percent
recovery determinations indicate the accuracy of the analysis at recovering
actual analytical method compounds from the matrix. Relative percent
difference determinations calculated from a comparison of the MS/MSD
recoveries demonstrate the precision of the analytical method. Actual
percent recovery and relative percent difference data is displayed alongside
their respective acceptable analytical method performance limits in the QA/QC
section of the report. The MS/MSD are considered in control when the
precision is wi thin established control limits and the associated check
sample has been found to be acceptable. A minimum of ten percent (10%) of
all analyses are MS/MSD quality control samples.
**********************************EXAMPLE*********************************
COMPOUND SAMPLE MS MSD RPD QC LIMITS
CONC. %REC %REC RPD RECOVERY
4,4'-DDT 0 95 112 16 22 66-119
Benzene 10 86 93 8 20 39-150
(cmpd. name) sample 1st% 2nd% Rel.% accep. method
result recov. recov. diff. perform range
Analvtical Result Qualifiers
The following qualifiers, as defined below, may be appended to analytical
results in order to allow proper interpretation of the results presented:
J - indicates an estimated concentration (typically used when a dilution,
matrix interference or instrumental limitation prevents accurate quantitation
of a particular analyte).
B - indicates the presence of a particular analyte in the laboratory blank
analyzed concurrently with the samples. Results must be interpreted
accordingly.
OIL - indicates that because of matrix interferences and/or high analyte
concentrations, it was necessary to dilute the sample to a point where the
surrogate or spike concentrations fell below a quantifiable amount and could
not be reported.
I
I .1 ENSECO-WADSWORTH/ALERT
Laboratories
ICOMPANY: MISSIMER & ASSOCIATES, INC.
LAB #: 3A0810-BK
rJ'lATRIX: WATER
.SAMPLE ID: LABORATORY BLANK
DATE RECEIVED: '
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
NA
1/12/93
I
I
CERTIFICATION-#: E84059
VOLATILE ORGANICS BRS84297
USEPA METHOD 624 - GC/MS
IAcrolein
Acrylonitrile
renzene
Bromodich1oromethane
Bromoform
IBromomethane
Carbon tetrachloride
ICh1orobenzene
Chloroethane
ND* 1,1-Dichloroethene ND
ND* 1,2-Dichloroethene{Total) ND
ND 1,2-Dichloropropane ND
ND cis-1,3-Dichloropropene ND
ND trans-1,3-Dich1oropropene ND
ND Ethy1benzene ND
ND Methylene chloride ND
ND 1,1,2,2-Tetrachloroethane ND
ND Tetrachloroethene ND
ND Toluene ND
ND 1, 1, 1-Trichloroethane ND
ND 1,1,2-Trichloroethane ND
ND Trichloroethene ND
ND Trich1orofluoromethane ND
ND Vinyl chloride ND
ND Xylene (Total) ND
ND
ND
12-ChloroethY1VinYl ether
Chloroform
Chloromethane
IDibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
11,4-Dichlorobenzene
1,1-Dichloroethane
11,2-Dich1oroethane
I
NOTE:
I
I
ND
ND*
ND**
J
B
(None Detected, lower detectable limit = 1
(None Detected, lower detectable limit = 10
(None Detected, lower detectable limit =
(Detected, but below quantitation limit; estimated
(Compound detected in method blank associated with
(Not Analyzed)
ug/L) as rec'd
ug/L) as rec'd
ug/L) as rec'd
value)
this sample),
SURROGATE RECOVERY:
11,2-Dich1oroethane
To1uene-d8
IBromofluorobenzene
%
ACCEPTABLE LIMITS
WATER SOLID
(75-123) (85-126)
(75-123) (89-124)
(86-115) (84-124)
LOW LEVEL
(85 -13 8)
(89-128)
(83 -128)
94
97
97
I
I IFI ENSECO-WADSVWORTH/ALERT
. Laboratories
~OMPANY: MISSIMER & ASSOCIATES, INC.
LAB #: 3A0810-BK
rflATRIX: WATER
IsAMPLE ID: LABORATORY BLANK
I
I
DATE RECEIVED: .
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
NA
1/19/93
CERTIFICATION #: E840S9
VOLATILE ORGANICS BRS84297
USEPA METHOD 624 - GC/MS
IAcrolein
Acrylonitrile
renzene
Bromodichloromethane
~romoform
rromomethane
Carbon tetrachloride
IChlorobenzene
Chloroethane
12-ChloroethYlVinYl ether
Chloroform
Chloromethane
.nibromochloromethane
~,2-Dich1orobenzene
1,3-Dichlorobenzene
Il,4-Dichlorobenzene
1,1-Dichloroethane
11,2-Dichloroethane
I
NOTE:
I
I
ND
ND.
ND..
J
B
(None Detected, lower detectable limit = 1
{None Detected, lower detectable limit = 10
(None Detected, lower detectable limit =
{Detected, but below quantitation limit; estimated
{Compound detected in method blank associated with
(Not Analyzed)
ug/L) as rec'd
ug/L) as rec'd
ug/L) as rec'd
value)
this sample)
SURROGATE RECOVERY:
11,2-Dichloroethane
To1uene-d8
IBromof1uorobenzene
ND. 1,1-Dichloroethene ND
ND. 1,2-Dichloroethene(Total) NO
NO 1,2-Dichloropropane NO
ND cis-1,3-Dichloropropene ND
ND trans-1,3-Dichloropropene ND
ND Ethy1benzene ND
NO Methylene chloride 3
ND 1, 1, 2, 2-Tetrachloroethane NO
ND Tetrachloroethene NO
ND Toluene NO
ND 1, 1, l-Trichloroethane NO
ND 1,1,2-Trichloroethane NO
ND Trich1oroethene ND
ND Trichlorofluoromethane ND
ND Vinyl chloride ND
ND Xylene (Total) NO
ND
ND
%
ACCEPTABLE LIMITS
WATER SOLID
(75 -123 ) ( 8 5 -126 )
(75-123) (89-124)
(86-115) (84-124)
LOW LEVEL
(85-138)
(89-128)
(83-128)
100
102
106
iii ENSECO-WADSWORTH/ALERT
Lablratories
ICOMPANY: MISSIMER & ASSOCIATES,
LAB #: 3A0810-BK
MATRIX: WATER
ISAMPLE ID: LABORATORY BLANK
I
1
INC.
DATE RECEIVED:
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/18/93
I
I
CERTIFICATION #: E84059
BASE/NEUTRAL -- EXTRACTABLE ORGANICS HRS84297
USEPA METHOD 625 - GC/MS (1 of 2)
IAcenaPhthene
Acenaphthylene
IAn thracene
Benzidine
Benzo(a)anthracene
IBenZO(b)fluoranthene
Benzo(k)fluoranthene
IBenzo (ghi) perylene
Benzo (a) py:t'ene
NO
ND
NO
Dibenzo(a,h)anthracene
Di-n-butyl phthalate
1,2-Dichlorobenzene
NO
NO
ND
NO.
NO
NO
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
NO
NO
NO.
NO
NO
ND
Diethyl phthalate
Dimethyl phthalate
2,4-Dinitrotoluene
NO
NO
NO
IBis {2-Chloroethoxy)methane ND
Bis{2-Chloroethyl)ether NO
Bis (2-Chloroisopropyl) ether NO
2,6-Dinitrotoluene NO
Di-n-octyl phthalate NO
Fluoranthene NO
IBis (2-Ethylhexy1)phtha1ate
4-Bromophenyl phenyl ether
Butyl benzyl phthalate
12 - Chloronaphthalene
4-Chlorophenyl phenyl
I Chrysene
ND
NO
NO
Fluorene NO
Hexach1orobenzene NO
Hexachlorobutadiene ND
NO
ether NO
NO
Hexachlorocyc1opentadiene NO
Hexachloroethane NO
Indeno(1,2,3-cd)pyrene NO
I
I NOTE:
NO
NO.
J
B
(None Detected, lower detectable limit = 10
(None Detected, lower detectable limit = 50
(Detected, but below quantitation limit; estimated
{Compound detected in method blank associated with
(Not Analyzed)
ug/L) as rec'd
ug/L) as rec'd
value)
this sample)
I
I
I
. ENSECO-WADSVWORTH/ALERT
Laboratories
I COMPANY: MISSIMER & ASSOCIATES,
LAB #: 3A0810-BK
MATRIX: WATER
I SAMPLE ID: LABORATORY BLANK
I
I
INC.
DATE RECEIVED: .
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/18/93
CERTIPICATION #: E84059
BASE/NEUTRAL EXTRACTABLE ORGANICS BRS84297
USEPA METHOD 625 - GC/MS (2 of 2)
I
I
I Isophorone
Naphthalene
Nitrobenzene
IN-Nitrosod~ethYlamine
N-Nitrosodiphenylamine
N-Nitrosodi-n-propy1amine
I Phenanthrene
pyrene
11,2,4-Trichlorobenzene
I
I
I
I
I
I NOTE: NO
NO*
J
I B
NO
ND
ND
ND
ND
ND
ND
ND
NO
{None Detected, lower detectable limit . 10
(None Detected, lower detectable limit . SO
{Detected, but below quantitation limit: estimated
{Compound detected in method blank associated with
(Not Analyzed)
I SURROGATE RECOVERY:
Nitrobenzene-d5
I Pluorobiphenyl
Terphenyl-d14
ug/L) as rec'd
ug/L) as rec'd
value)
this sample)
"
ACCEPTABLE LIMITS
WATER SOLID
(22-135) (10-155)
(34-140) (12-153)
(10-132) (13 -140)
85
76
86
I
I
.1 ENSECO-WADSVWORTH/ALERT
Laboratories
1 COMPANY: MISSIMER & ASSOCIATES,
LAB #: 3A0810-BK
MATRIX: WATER
I SAMPLE ID: LABORATORY BLANK
INC.
1
I
DATE RECEIVED: .
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/18/93
ACID EXTRACTABLE ORGANICS
USEPA METHOD 625 - GC/MS
CERTIPICATION #: E84059
HRS84297
14 -Ch1oro-3 -methylphenol
2-Chlorophenol
12,4 -Dichlorophenol
2,4-Dimethy1pheno1
2,4-Dinitropheno1
12-MethYl-4,6-dinitroPheno1
2-Nitrophenol
14-NitroPhenol
Pentachlorophenol
ND
ND
ND
ND
ND.
ND.
ND
ND.
ND.
I Phenol
2,4,6-Trichlorophenol
ND
ND
I
I
I
I
.1 NOTE: ND
ND.
J
I B
(None Detected, lower detectable ltmit = 10
(None Detected, lower detectable ltmit = 50
{Detected, but below quantitation ltmit; estimated
{Compound detected in method blank associated with
(Not Analyzed)
I SURROGATE RECOVERY:
2-P1uorophenol
Phenol-d5
12,4,6-TribromoPhenol
"
58
71
70
ACCEPTABLE LIMITS
WATER SOLID
(17-95) (24-118)
(11-89) (17-124)
(10-134) (10-156)
ug/L) as rec'd
ug/L) as rec'd
value)
this sample)
. ENSECO-WADSWORTH/ALERT
Laboratories
ICOMPANY: MISSIMER & ASSOCIATES,
LAB #: 3A0810-BK
MATRIX: WATER
I SAMPLE ID: LABORATORY BLANX
I
I
INC.
DATE RECEIVED:.
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/18/93
I
1
I
11-MethY1naPhthalene
2-Methylnaphthalene
I
1
I
I
I
1
CERTIFICATION #: E84059
HRS84297
SELECTED ORGANIC COMPOUNDS ANALYTICAL REPORT
PARAMETER
RESULT (ug /L )
DETECTION
LIMIT
ND
ND
5
5
I NOTE:
ND
J
(None Detected) as rec'd
(Detected, but below quantitation limit; estimated value)
I SURROGATE RECOVERY:
ACCEPTABLE LIMITS
WATER SOLID
%
I Ni trobenzene - d5
2-Fluorobiphenyl
Terphenyl-d14
(22 -135)
(34-140)
(10 -132 )
(10-155)
(12-153)
(13 -140)
85
78
86
I
1
FI ENSECO-WADSVWORTH/ALERT
. Laboratories
ICOMPANY: MISSIMER &: ASSOCIATES,
LAB #: 3A0810-BK
MATRIX: WATER
ISAMPLE ID: LABORATORY BLANK
I
I
INC.
DATE RECEIVED: ,
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/13/93
I
I
I
CERTIFICATION #: E84059
CHLORINATED PESTICIDES BRS84297
METHOD 608 LIST - GC
IAlPha - BHC
Beta-BHC
Delta-BHC
RESULT (mg /L ) DETECTION LIMIT
NO 0.1
NO 0.1
NO 0.1
NO 0.1
NO 0.1
ND 0.1
NO 0.1
NO 0.1
NO 0.1
NO 0.1
NO 0.1
NO 0.1
ND 0.1
NO 0.1
NO 0.1
NO 0.1
NO 1
NO 4
ILindane
Heptachlor
Aldrin
IHeptach10r Epoxide
Endosulfan I
IDieldrin
4,4'-DDE
Endrin
IEndosulfan II
4 , 4' - DDD
IEndrin Aldehyde
Endosulfan Sulfate
4,4'-DDT
IChlordane
Toxaphene
I
INOTE: ND
(None Detected) as rec'd
(Not Analyzed)
I SURROGATE RECOVERY:
Tetrachloro(m)xy1ene
I Dibutylchlorendate
%
ACCEPTABLE
WATER
(33 -122 )
(18-129)
LIMITS
SOLID
(32 -154)
(27 -139)
86
89
I
II ENSECO-WADSWORTH/ALERT
Laboratories
I COMPANY : MISSIMER &: ASSOCIATES,
LAB #: 3A0810-BK
MATRIX: WATER
ISAMPLE ID: LABORATORY BLANK
I
I
INC.
DATE RECEIVED:,
DATE EXTRACTED:
DATE ANALYZED:
1/ 8/93
1/11/93
1/13/93
1
I
CERTIFICATION #: E84059
POLYCHLORINATED BIPHENYLS HRS84297
METHOD 608 LIST - GC
IPCB-1016
PCB-1221
PCB-1232
IpCB-1242
PCB-1248
PCB-1254
IpCB-1260
ND
ND
ND
ND
ND
ND
ND
1
I
I
I
I
1
NOTE:
I
ND
ND*
(None Detected, lower detectable limit = 1
(None Detected, lower detectable limit =
(Not Analyzed)
mg/L) as rec'd
mg/L) as rec'd
SURROGATE RECOVERY:
I Tetrachloro(m)xylene
%
ACCEPTABLE LIMITS
WATER SOLID
(33-122) (32-154)
86
I
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. ENSECO-WADSVWORTH/ALERT
Laboratories
ICOMPANY : MISSIMER &: ASSOCIATES,
LAB #: 3A0810-BK
MATRIX : WATER
I SAMPLE ID : LABORATORY BLANK
INC.
DATE RECEIVED:, 1/ 8/93
I
CERTIFICATION #: E84059
METALS ANALYTICAL REPORT HRS84297
SELECTED LIST
ITotal metals analysis results - as received
I
ELEMENT
ISilver
Arsenic
Beryllium
1 Cadmium
Chromium
I Copper
Mercury
INickel
Lead
Antimony
I Selenium
Thallium
I Zinc
I
1
I NOTE: NO
(None Detected)
I
I
I
PREPARATION - DETECTION
ANALYSIS DATE RESULT LIMIT
1/11/93 NO 50 ug/L
1/11/93 NO 10 ug/L
1/11/93 NO 50 ug/L
1/11/93 NO 10 ug/L
1/11/93 NO 50 ug/L
1/11/93 NO 50 ug/L
1/12/93 NO 2 ug/L
1/11/93 NO 50 ug/L
1/11- 1/12/93 NO 5 ug/li
1/11- 1/12/93 NO 300 ug/L
1/11/93 NO 5 ug/L
1/11- 1/12/93 NO 10 ug/L
1/11/93 NO 50 ug/L
I
I
liIiIifl ENSECO-WADSWORTH/ALERT
. Laboratories
ICOMPANY : MISSIMER & ASSOCIATES,
LAB #: 3A0810-BK
MATRIX : WATER
I SAMPLE ID : LABORATORY BLANK
1
I
1 PARAMETER
INC.
ANALYTICAL REPORT
DATE RECEIVED:. 1/ 8/93
CERTIFICATION #: E84059
BRS84297
I Cyanide
Nitrate-Nitrite Nitrogen
Total Recoverable Phenolics
I
1
I
I
I
I
I
I NOTE:
(None Detected)
ND
I
I
I
PREPARATION -
ANALYSIS DATE
1/19/93
1/14/93
1/14/93
RESULT
DETECTION
LIMIT
ND
ND
ND
mg/L
mg/L
mg/L
0.005
0.05
0.05
I
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1
I
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I
1
I
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I
1
I
I
.
ENSECO-WVADSVWORTH/ALERT
Laboratories
LAB ID
MATRIX
METHOD
RUN ID
LCS
WATER
624
A5025
DATE EXTRACTED: N/A
DATE ANALYZED: 01/12/92
LABORATORY CONTROL SAMPLE RESULTS
COMPOUND
ANALYTICAL
RUN ID #
QC LIMITS
RPD %REC
LCS
%REC
---------------------------------------------------------------------------
1,1-Dichloroethene A5025 95 40 56-133
Trichloroethene 90 20 67-106
Chlorobenzene 85 21 78-122
Toluene 98 30 64-128
Benzene 96 21 83-123
Dichlorobromomethane 81 25 71-123
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1
I
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I
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.
ENSECO-WADSWORTH/ALERT
Laboratories
LAB ID
MATRIX
METHOD
RUN ID
LCS
WATER
624
A5079
DATE EXTRACTED: N/A
DATE ANALYZED: 01/19/93
LABORATORY CONTROL SAMPLE RESULTS
COMPOUND
ANALYTICAL
RUN ID #
QC LIMITS
RPD %REC
LCS
%REC
---------------------------------------------------------------------------
1,1-Dichloroethene A5079 110 40 56-133
Trichloroethene 100 20 67-106
Chlorobenzene 89 21 78-122
Toluene 111 30 64-128
Benzene 115 21 83-123
Dichlorobromomethane 100 25 71-123
I
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I
I
I
I
I
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LAB ID
MATRIX
METHOD
RUN 10
COMPOUND
---------------------------------------------------------------------------
ENSECO-WADSVWORTH/ALERT
Labontories
LCS
WATER
625
A0260
DATE EXTRACTED: 01/11/93
DATE ANALYZED: 01/18/93
LABORATORY CONTROL SAMPLE RESULTS
ANALYTICAL
RUN 10 #
1,4-Dichlorobenzene A0260
N-Nitrosodi-n-propylamine
1,2,4 Trichlorobenzene
Acenaphthene
2,4-Dinitrotoluene
Pyrene
LCS
%REC
87
52
84
89
63
85
QC LIMITS
RPD %REC
29 17-104
43 36-124
30 20-109
37 54-129
32 27-123
47 34-128
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ENSECO-VWADSVWORTH/ALERT
Laboratories
LAB ID
MATRIX
METHOD
RUN ID
LCS
WATER
625
A0260
DATE EXTRACTED: 01/11/93
DATE ANALYZED: 01/18/93
LABORATORY CONTROL SAMPLE RESULTS
COMPOUND
ANALYTICAL
RUN ID 1#
QC LIMITS
RPD %REC
LCS
%REC
---------------------------------------------------------------------------
Phenol A0260 95 45 17-108
2-Chlorophenol 81 37 10-118
4-Chloro-3-methylphenol 89 48 23-121
4-Nitrophenol 54 56 10-142
Pentachlorophenol 54 49 10-128
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ENSECO-WADSVWom/ALERT
Laboratories
LAB ID
MATRIX
METHOD
RUN ID
LCS
WATER
608
S00121
DATE EXTRACTED: 01/11/93
DATE ANALYZED: 01/13/93
LABORATORY CONTROL SAMPLE RESULTS
COMPOUND
ANALYTICAL
RUN ID 41
QC LIMITS
RPD %REC
LCS
%REC
---------------------------------------------------------------------------
Lindane SOO121 82 33 49-116
Heptachlor 80 28 62-119
Aldrin 83 15 65-110
Dieldrin 99 35 38-143
Endrin 76 36 45-117
4,4'-DDT 85 39 46-126
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ENSECO-VWADSVWORTH/ALERT
Laboratories
LAB ID
LCS
MATRIX
WATER
LABORATORY CONTROL SAMPLE RESULTS
METALS
DATE DATE LCS QC LIMITS
ELEMENT PREPARED ANALYZED %REC RPD %REC
---------------------------------------------------------------------------
Antimony 01/11/93 01/12/93 104 21 79-122 LCS
Arsenic (furnace) 11/11/93 01/11/93 87 38 53-131
Beryllium 01/11/93 01/11/93 103 18 81-118
Cadmium 01/11/93 01/11/93 80 18 77-113
Chromium 01/11/93 01/11/93 98 21 79-121
Copper 01/11/93 01/11/93 97 19 80-119
Lead (furnace) 01/11/93 01/12/93 107 33 64-132
Mercury (vapor) 01/12/93 01/12/93 99 18 83-120
Nickel 01/11/93 01/11/93 96 13 84-111
Selenium (furnace) 01/11/93 01/11/93 69 38 54-130
Silver 01/11/93 01/11/93 104 23 74-121
Thallium (furnace) 01/11/93 01/12/93 94 31 56-120
Zinc 01/11/93 01/11/93 97 19 77-116
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LAB ID
PARAMETER
---------------------------------------------------------------------------
78
24 49-112
LCS
ENSECO-WADSWORTH/ALERT
Laboratories
LCS
Total Recoverable
Phenolics
Cyanide
MATRIX
WATER
LABORATORY CONTROL SAMPLE RESULTS
WET CHEMISTRY
DATE DATE
PREPARED ANALYZED
01/14/93 01/14/93
01/19/93 01/19/93
LCS
%REC
QC LIMITS
RPD %REC
102
25 63-114
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